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WebMar 8, 2024 · In peptide chemistry, little attention has been paid to the tetrahydropyranyl (Thp) group, ... Thp has the advantage over benzyl-based protecting groups, such as Trt, diphenylmethyl (Dpm), (4-methoxyphenyl)diphenylmethyl (methoxytrityl, Mmt) or benzyloxymethyl (Bom), because it lacks aromaticity and offers better solubility. ... WebMar 16, 2024 · Chemical synthesis of thioether-bonded bicyclic peptides requires the use of two orthogonal Cys protecting groups to ensure the correct connectivity of two thioether bonds [10].Many types of Cys protecting groups have been developed, including Mmt deprotected under weakly acidic conditions, Dpm (Trt, Mob and Meb) deprotected under … shelly williams attorney in mt sterling ky
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